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    Laser Magnetic Resonance of the O2 Molecule Using 119-and 78-μm H2 O Laser Lines

    K. M. Evenson

    Masataka Mizushima

    • National Bureau of Standards, Quantum Electronics Division, Boulder, Colorado 80302

    • Department of Physics and Astrophysics, University of Colorado, Boulder, Colorado 80302

    Phys. Rev. A 6, 2197 – Published 1 December, 1972

    DOI: https://doi.org/10.1103/PhysRevA.6.2197

    Abstract

    Laser magnetic resonance of the O2 molecule is observed using the 119- and 78-μm lines of the H2 O laser. The relevant transitions for the 119-μm line are (N=13, J=14, M)→(N=15, J=14, M′), and those for the 78-μm line are (N=21, J=22, M)→(N=23, J=22, M′), where M′=M or M±1 depending on the polarization. It is found that g⊥=2.0044±0.0008, gz=2.0020±0.0001, gn=0.000125±0.000008 give slightly better agreement between theory and experiment than Hendrie and Kusch's values (g⊥=2.005169, gz=2.001939, gn=0.000122) and Bauer, Kamper, and Lustig's values (g⊥=2.004838, gz=2.002025, gn=0.000126), but the present experimental accuracy is not high enough to exclude these older g-factor values. Using the existing microwave data and the known laser frequencies, the zero-field frequencies for the transitions (N=J=13)→(N=J=15) and (N=J=21)→(N=J=23) are found to be 2496.283±0.30 and 3865.81±0.03 GHz, respectively. Combining these results with the frequency of the (N=J=1)→(N=J=3) transition obtained by McKnight and Gordy, we obtain B0=43.100518±0.000020 GHz, B1=−0.14496±0.00030 MHz, and B2=−0.17±1.00 Hz.

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