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    Hyperfine and Zeeman Interactions in the Metastable, cΠu3, State of H2

    A. Norman Jette

    • Applied Physics Laboratory, The Johns Hopkins University, Silver Spring, Maryland 20910

    Phys. Rev. A 5, 2009 – Published 1 May, 1972

    DOI: https://doi.org/10.1103/PhysRevA.5.2009

    Abstract

    The magnetic hyperfine and gF constants were calculated for the cΠu3(1s, 2p) metastable state of H2 using wave functions determined from the optimal-double-configuration model. The hyperfine constants differ by as much as 24% from previous values obtained using a single-configuration electronic wave function. The hyperfine constants are a=21.98 MHz, b=471.14 MHz, c=59.37 MHz, d=−12.87 MHz, where a and b are the orbital interaction of the electron with the nucleus and the Fermi contact interaction, respectively, and c and d arise from the dipolar interaction of electron and nucleus. With these values for the hyperfine constants, along with the experimental fine-structure splittings and a matrix-diagonalization procedure, the gF values were calculated and found to be in better agreement with experiment than the earlier theoretical values.

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