Hyperfine and Zeeman Interactions in the Metastable, , State of
Phys. Rev. A 5, 2009 – Published 1 May, 1972
DOI: https://doi.org/10.1103/PhysRevA.5.2009
Abstract
The magnetic hyperfine and constants were calculated for the metastable state of using wave functions determined from the optimal-double-configuration model. The hyperfine constants differ by as much as 24% from previous values obtained using a single-configuration electronic wave function. The hyperfine constants are MHz, MHz, MHz, MHz, where and are the orbital interaction of the electron with the nucleus and the Fermi contact interaction, respectively, and and arise from the dipolar interaction of electron and nucleus. With these values for the hyperfine constants, along with the experimental fine-structure splittings and a matrix-diagonalization procedure, the values were calculated and found to be in better agreement with experiment than the earlier theoretical values.