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    Variation-Perturbation Treatment of Scattering Problems. I. Potential Scattering by a Central Field

    Stephen K. Knudson and Bernard Kirtman

    • Department of Chemistry, University of California, Santa Barbara, California 93106

    Phys. Rev. A 3, 972 – Published 1 March, 1971

    DOI: https://doi.org/10.1103/PhysRevA.3.972

    Abstract

    A variation-perturbation treatment of potential scattering by a central field is presented. The first-order correction Xl(1), to the lth partial wave, which gives the phase shift ηl, through third order, may be determined from a variation principle or as the solution of an inhomogeneous differential equation. Optimization of the initial approximation by means of the Hulthén condition yields a vanishing ηl(1) and a bound Xl(1). Encouraging results are obtained in trial calculations on the exponential and Yukawa potentials treated as perturbed spherical holes. The likelihood of extending this approach to include the most powerful techniques of bound-state perturbation theory is anticipated.

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