Binding of Two Closed-Shell Atoms on a Solid Surface
Phys. Rev. A 3, 1133 – Published 1 March, 1971
DOI: https://doi.org/10.1103/PhysRevA.3.1133
Abstract
The interaction of two noble-gas atoms on a solid surface is studied with a view to finding conditions under which they form a bound state. Two limiting models for the surface are considered - a flat surface which constrains the atoms to move in two dimensions and imposes no further restriction on their motion, and a surface consisting of a periodic arrangement of potential wells separated by large barriers, to which the tight-binding method is applicable. A curious feature of the result for the binding energy is shown to be a consequence of the fact that the problem is two dimensional.