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    Tests of the Wannier Expressions for Diffusion Coefficients of Gaseous Ions in Electric Fields

    E. W. McDaniel

    J. T. Moseley

    • School of Physics, Georgia Institute of Technology, Atlanta, Georgia 30332

    • Stanford Research Institute, Menlo Park, California 94025

    Phys. Rev. A 3, 1040 – Published 1 March, 1971

    DOI: https://doi.org/10.1103/PhysRevA.3.1040

    Abstract

    All of the published experimental values of longitudinal and transverse diffusion coefficients of gaseous ions in electric fields, except those cases dominated by resonant charge transfer, are compared with the predictions of Wannier's theory. The products of the measured coefficients and the gas number density appear to vary as vd3(EN)−1, where vd is the ionic drift velocity, in agreement with Wannier's predictions. Here EN is the ratio of the electric drift field intensity to the gas number density. In addition, the absolute agreement between experiment and theory is quite satisfactory.

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