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Hyperfine anomaly in mercury and test of the Moskowitz-Lombardi rule

J. Vandeleur, G. Sanamyan, B. M. Roberts, and J. S. M. Ginges

Phys. Rev. A 111, L050801 – Published 2 May, 2025

DOI: https://doi.org/10.1103/PhysRevA.111.L050801

Abstract

We test the Moskowitz-Lombardi rule, originally formulated for mercury, which gives a simple relation between the magnetic moment of an atomic nucleus and the effect of its radial distribution on the hyperfine structure: the magnetic hyperfine anomaly or Bohr-Weisskopf (BW) effect. While the relation for the differential effect between isotopes may be completely determined experimentally, the value for the additive constant that is needed to give the BW effect for a single isotope has remained unverified. In this work, we determine the BW effect in H-like, singly ionized, and neutral mercury isotopes from experimental muonic-Hg199 data together with differential anomalies and our atomic calculations. We check this result by directly extracting the BW effect from the measured hyperfine constant for Hg+199 using state-of-the-art atomic many-body calculations. From this we deduce an empirical value for the additive constant in the Moskowitz-Lombardi rule, which differs significantly from the values advocated previously. This result allows for increased precision in calculations of the hyperfine structure and improved tests of atomic and nuclear theory.

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