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  • Letter

Single quantum emitters with spin ground states based on Cl bound excitons in ZnSe

Aziz Karasahin1,*, Robert M. Pettit1,2, Nils von den Driesch3,4, Marvin Marco Jansen3,4, Alexander Pawlis3,4, and Edo Waks1,†

  • 1Institute for Research in Electronics and Applied Physics, Department of Electrical and Computer Engineering and Joint Quantum Institute, University of Maryland, College Park, Maryland 20742, USA
  • 2Intelligence Community Postdoctoral Research Fellowship Program, University of Maryland, College Park, Maryland 20742, USA
  • 3Peter-Grünberg-Institute (PGI-9), Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
  • 4JARA-FIT (Fundamentals of Future Information Technology), Jülich-Aachen Research Alliance, 52062 Aachen, Germany

  • *azizk@umd.edu
  • †edowaks@umd.edu

Phys. Rev. A 106, L030402 – Published 19 September, 2022

DOI: https://doi.org/10.1103/PhysRevA.106.L030402

Abstract

Defects in wide-band-gap semiconductors are promising qubit candidates for quantum communication and computation. Epitaxially grown II-VI semiconductors are particularly promising host materials due to their direct band gap and potential for isotopic purification to a spin-zero nuclear background. Here, we show an alternative type of single photon emitter with potential electron spin qubits based on Cl impurities in ZnSe. We utilize a quantum well to increase the binding energies of donor emission and confirm single photon emission with short radiative lifetimes of 192 ps. Furthermore, we verify that the ground state of the Cl donor complex contains a single electron by observing two-electron-satellite emission, leaving the electron in higher orbital states. We also characterize the Zeeman splitting of the exciton transition by performing polarization-resolved magnetic spectroscopy on single emitters. Our results suggest single Cl impurities are suitable as a single photon source with a potential photonic interface.

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