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Linear polarization fractions of Fulcher-α fluorescence in electron collisions with H2

Liam H. Scarlett1,*, Una S. Rehill1, Mark C. Zammit2, Klaus Bartschat3, Igor Bray1, and Dmitry V. Fursa1

  • 1Curtin Institute for Computation and Department of Physics, Astronomy and Medical Radiation Sciences, Curtin University, Perth, Western Australia 6102, Australia
  • 2Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA
  • 3Department of Physics and Astronomy, Drake University, Des Moines, Iowa 50311, USA

  • *liam.scarlett@postgrad.curtin.edu.au

Phys. Rev. A 104, L040801 – Published 12 October, 2021

DOI: https://doi.org/10.1103/PhysRevA.104.L040801

Abstract

We apply the molecular convergent close-coupling method to the calculation of linear polarization fractions for Fulcher-band fluorescence following electron-impact excitation of the H2 d3Πu state. The results exhibit the opposite threshold behavior compared to the only previous calculations [Meneses, Brescansin, Lee, Michelin, Machado, and Csanak, Phys. Rev. A 52, 404 (1995)], but are in agreement with the most recent measurements for the Q(1), R(1), and Q(3) transitions [Maseberg, Bartschat, and Gay, Phys. Rev. Lett. 111, 253201 (2013)].

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