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    High-precision measurement of the 2s2pP1o1 center of gravity in neutral Be9 at the parts-per-billion level

    K. J. Ahrendsen, E. M. Kay, and W. D. Williams*

    • Physics Department, Smith College, Northampton, Massachusetts 01063, USA

    • *Contact author: wraven@smith.edu

    Phys. Rev. A 112, 012819 – Published 23 July, 2025

    DOI: https://doi.org/10.1103/8b1f-fpgq

    Abstract

    We use saturated absorption spectroscopy to study neutral Be9 atoms produced in a dc discharge lamp. Previous measurements of the 2s2pPo1 state energy were limited in precision due to overlapping hyperfine structure. In this work, we apply a 400 G magnetic field, which splits the magnetic sublevels creating a spectral feature near the center-of-gravity energy of the state. We determine the transition frequency from the ground state to be 1276080105.5(1.2)MHz, corresponding to a center-of-gravity energy of 42565.45058(4)cm−1. This result is a factor of 30 more precise than the previous best measurement and constitutes the most precise determination of an excited-state energy in a four-electron system to date. As theoretical methods advance, this result will enable stringent tests of quantum electrodynamics in four-electron systems.

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