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    Coherent and incoherent control of ionization-fragmentation dynamics in H2 driven by a two-color laser field

    JinPeng Ma1, CongCong Jia1, Ting Xu1, SiQi Pei1, YinSong Tang1, HaoDong Ju1, XiaoQing Hu1,*, Yong Wu1,2, and JianGuo Wang1

    • *Contact author: xiaoqing-hu@foxmail.com

    Phys. Rev. A 112, 013120 – Published 25 July, 2025

    DOI: https://doi.org/10.1103/6xf5-b3t7

    Abstract

    We utilize the time-dependent wave-packet propagation method to simulate the complete fragmentation dynamics of H2 molecules subjected to the two-color field. The study focuses on elucidating the influence of the carrier-envelope phase (CEP) difference between the two laser beams on key dynamical properties, including the alignment of neutral molecules, ionization probability, dissociation probability, proton angular distribution, and kinetic energy release (KER). Our study shows that two-color fields can simultaneously provide coherent and incoherent modulations of molecular dynamics. For neutral molecular alignment, two-color modulation proves ineffective as it depends quadratically on intensity rather than wave properties. However, strong-field ionization's inherent nonlinearity enables coherent control through intensity-dependent angular distributions and ionization probabilities. Examining H2+ fragmentation dynamics, we observe coexisting first-, second-, and third-order processes under two-color irradiation. First-order transitions exhibit incoherent modulation via laser component competition, altering vibrational distributions and KER spectra phase independently. The second-order ω2−ω1 process repopulates bound states but minimally affects fragmentation. Crucially, at high intensities, the dominant third-order ω2−ω1+ω1 process enables phase-dependent coherent control through reexcitation of second-order-created bound states, revealing fundamental insights into multiorder process interplay in strong-field molecular dynamics.

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