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    High-precision EUV spectroscopy of the 2s2pP11−2s2 S01 transition in Be-like S12+ and Cl13+: Test of QED effects

    X. P. Zhou1,2, X. Liu3, W. Q. Wen1,2,4,*, Y. Yuan1,2, H. K. Huang1,2, Z. K. Huang1,2, H. B. Wang1,2, M. Y. Wan1, J. Xiao3,† et al.

    Y. S. Kozhedub5,‡, A. V. Malyshev5,6, V. M. Shabaev5,6, J. G. Li7, S. F. Zhang1,2, and X. Ma1,2

    • *Contact author: wenweiqiang@impcas.ac.cn
    • †Contact author: xiao_jun@fudan.edu.cn
    • ‡Contact author: y.kozhedub@spbu.ru

    Phys. Rev. A 112, 062815 – Published 15 December, 2025

    DOI: https://doi.org/10.1103/5dls-tz48

    Abstract

    High-accuracy extreme ultraviolet (EUV) spectroscopy of the 1s22s2p P11−1s22s2 S01 electric dipole (E1) transitions in beryllium-like S12+ and Cl13+ was performed at the Shanghai High-Temperature Superconducting Electron Beam Ion Trap. Utilizing a portable high-resolution soft x-ray and EUV spectrometer, the measured E1 transition wavelengths for S12+ and Cl13+ were determined to be 256.6852(53)Å and 237.8037(62)Å (in vacuum), achieving relative uncertainties of 21 ppm and 26 ppm, respectively. Furthermore, the E1 transition energies for these ions were evaluated with ultra-high precision within an ab initio quantum electrodynamics (QED) framework to enable a stringent comparison with the experimental data. The measured values are in good agreement with the theoretical predictions, providing a precision test of QED and correlation effects in few-electron highly charged ions.

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