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    2P1,3, 3P1,3, and 4P1,3 States of He and the 2P1 State of Li+

    B. Schiff, H. Lifson, C. L. Pekeris, and P. Rabinowitz

    • Department of Applied Mathematics, Weizmann Institute of Science, Rehovoth, Israel

    Phys. Rev. 140, A1104 – Published 15 November, 1965

    DOI: https://doi.org/10.1103/PhysRev.140.A1104

    Abstract

    A method is outlined for calculating nonrelativistic eigenvalues and wave functions for a two-electron P state of odd parity, and for evaluating the mass polarization and all of the relativistic corrections, apart from the radiative terms. Calculations have been made for the low-lying P states of He and the 2P1 state of Li+ using up to 560 terms in expansion of the wave function. The nonrelativistic eigenvalues converge to within an accuracy of from 104 cm1 to 102 cm1. The values of the mass polarization and of the relativistic corrections converge more rapidly than this, so that the total theoretical ionization energy is estimated to be correct to within an error of not more than 102 cm1, i.e., considerably less than the experimental error, in the case of all of the states considered. The difference between the theoretical and experimental term values is in no case greater than 0.1 cm1 in absolute magnitude, and is presumed to be due to the contributions from the radiative terms, which have not been included in the calculation. The term value obtained for the 2P1 state of Li+ confirms the identification of the line at 9581.42 Å in the Li+ spectrum as belonging to the 2S12P1 transition.

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