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    Generalized Ginzburg-Landau Theory of Superconducting Alloys

    L. Tewordt*

    • Department of Physics, University of Illinois, Urbana, Illinois

    • *Present address: Institut für Angewandte Physik, Universität Hamburg, Germany.

    Phys. Rev. 137, A1745 – Published 15 March, 1965

    DOI: https://doi.org/10.1103/PhysRev.137.A1745

    Abstract

    The Ginzburg-Landau-Gorkov theory of superconducting alloys is generalized to arbitrary temperatures and magnitudes of the gap parameter Δ=|Δ|expiϕ. However, the theory is still based on the assumption that the integral equation for the Green's function can be solved in powers of vs=(2eAϕ)2m and successively higher space derivatives of |Δ| and vs. The averaging over the positions of the impurities is carried out by means of the ladder-diagram technique developed by Abrikosov and Gorkov. The results are presented in terms of the free-energy functional. The form of this functional is found to be close to that proposed by Ginzburg-Landau if |Δ| is close to the BCS gap ΔBCS(T) and varies slowly in space. A comparison of the magnitudes of the fourth- and second-order terms in the free-energy functional shows that the local theory is valid if: (1) |Δ| and vs vary slowly over distances ξ; and (2) λs=h2mvs>ξ. In the "dirty" limit (lξ0) the length ξ ranges from about (lξ0)12 to (TcT)(lξ0)12 as |Δ| varies from ΔBCS(T) to zero.

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