Fine Structure of the and States of Helium
Phys. Rev. 137, A1672 – Published 15 March, 1965
DOI: https://doi.org/10.1103/PhysRev.137.A1672
Abstract
Nonrelativistic eigenvalues accurate to one part in to have been obtained for the and states of helium by improving the method previously developed for calculating two-electron atom -state wave functions, and by including up to 560 terms in the expansion. The corresponding values for the fine-structure splitting of the two levels are accurate to between and , and the small discrepancy with experiment is presumed to be due to the neglect of quantum-electrodynamic correction terms of relative order in the calculation. The results for the state are in good agreement with those obtained recently by C. Schwartz.