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    Fine Structure of the 2P3 and 3P3 States of Helium

    B. Schiff, C. L. Pekeris, and H. Lifson

    • Department of Applied Mathematics, The Weizmann Institute of Science, Rehovoth, Israel

    Phys. Rev. 137, A1672 – Published 15 March, 1965

    DOI: https://doi.org/10.1103/PhysRev.137.A1672

    Abstract

    Nonrelativistic eigenvalues accurate to one part in 109 to 1010 have been obtained for the 2P3 and 3P3 states of helium by improving the method previously developed for calculating two-electron atom P-state wave functions, and by including up to 560 terms in the expansion. The corresponding values for the fine-structure splitting of the two levels are accurate to between 105 and 106 cm1, and the small discrepancy with experiment is presumed to be due to the neglect of quantum-electrodynamic correction terms of relative order α2 in the calculation. The results for the 2P3 state are in good agreement with those obtained recently by C. Schwartz.

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