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    An Antiferromagnetic Transition in Zinc Ferrite

    J. M. Hastings and L. M. Corliss

    • Department of Chemistry, Brookhaven National Laboratory, Upton, New York

    Phys. Rev. 102, 1460 – Published 15 June, 1956

    DOI: https://doi.org/10.1103/PhysRev.102.1460

    Abstract

    Neutron powder diffraction patterns have been obtained for zinc ferrite over the temperature range 2.7°K-300°K. The data strongly suggest that the compound undergoes a transition from a paramagnetic state to an antiferromagnetic state in the neighborhood of 9°K. Superlattice lines observed below this temperature can be indexed on a cubic unit cell whose edge is twice that of the chemical cell. A model consisting of an antiferromagnetic alternation of ferromagnetic "bands" is tentatively proposed and discussed in relation to the observed line intensities.

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