A new technique of microwave spectroscopy is proposed for application to excited states of short lifetime. If atoms are excited by electron bombardment, closely-spaced energy levels may be unequally populated. The radiation emitted in decay to lower states may have an angular distribution and polarization character correlated with the direction of bombardment. When such atoms are acted on by radio-frequency fields, transitions may occur between excited states which cause an observable change in the pattern of decay radiation. An analysis is made of the possibility of applying such a method to a determination of the finestructure patterns of the helium atom. After a review of previous optical spectroscopic work and theory of this fine structure, an old unsolved mystery concerning the polarization of collision light is discussed. The theory of the Zeeman effect is worked out in a form applicable to the microwave experiments. Expected transition frequencies and rf matrix elements, intensity changes and shape of resonance curves, Stark effect and singlet-triplet mixing are also considered. An estimate is made of the signal to be expected in the experiment described in the following paper.
- Received 1 August 1956
- Published in the issue dated January 1957
© 1957 The American Physical Society